Wednesday 25 December 2013

Diesel Oxidation Catalyst (DOC)

For compression-ignition, the most commonly used catalytic converter is the Diesel Oxidation Catalyst (DOC). This catalyst uses O2 (oxygen) in the exhaust gas stream to convert CO (carbon monoxide) to CO2 (carbon dioxide) and HC (hydrocarbons) to H2O (water) and CO2. These converters often operate at 90 percent efficiency, virtually eliminating diesel odor and helping to reduce visible particulates. These catalysts are not active for NOx reduction because any reductant present would react first with the high concentration of O2 in diesel exhaust gas.
Reduction in NOx emissions from compression-ignition engines has previously been addressed by the addition of exhaust gas to incoming air charge, known as EGR. In 2010, most light-duty diesel manufacturers in the U.S. added catalytic systems to their vehicles to meet new federal emissions requirements. There are two techniques that have been developed for the catalytic reduction of NOx emissions under lean exhaust conditions - (SCR) and the lean NOx trap or NOx. Instead of precious metal-containing NOx adsorbers, most manufacturers selected base-metal SCR systems that use a reagent such an ammonia to reduce the NOx into nitrogen. Ammonia is supplied to the catalyst system by the injection of urea into the exhaust, which then undergoes thermal decomposition and hydrolysis into ammonia. One trademark product of urea solution, also referred to as Diesel Exhaust Fluid (DEF), is adblue
 diesel exhaust contains relatively high levels of particulate matter (soot), consisting in large part of elemental carbon. Catalytic converters cannot clean up elemental carbon, though they do remove up to 90 percent of the soluble organic fraction, so particulates are cleaned up by a soot trap or (DPF). Historically, a DPF consists of a Cordierite or Silicon Carbide substrate with a geometry that forces the exhaust flow through the substrate walls, leaving behind trapped soot particles. Contemporary DPFs can be manufactured from a variety of rare metals that provide superior performance (at a greater expense). As the amount of soot trapped on the DPF increases, so does the back pressure in the exhaust system. Periodic regenerations (high temperature excursions) are required to initiate combustion of the trapped soot and thereby reducing the exhaust back pressure. The amount of soot loaded on the DPF prior to regeneration may also be limited to prevent extreme exotherms from damaging the trap during regeneration. In the U.S., all on-road light, medium and heavy-duty vehicles powered by diesel and built after 1 January 2007, must meet diesel particulate emission limits that means they effectively have to be equipped with a 2-Way catalytic converter and a diesel particulate filter. Note that this applies only to the diesel engine used in the vehicle. As long as the engine was manufactured before 1 January 2007, the vehicle is not required to have the DPF system. This led to an inventory runup by engine manufacturers in late 2006 so they could continue selling pre-DPF vehicles well into 2007.

Angular contact of ball bearing

An angular contact ball bearing uses axially asymmetric races. An axial load passes in a straight line through the bearing, whereas a radial load takes an oblique path that tends to want to separate the races axially. So the angle of contact on the inner race is the same as that on the outer race. Angular contact bearings better support "combined loads" (loading in both the radial and axial directions) and the contact angle of the bearing should be matched to the relative proportions of each. The larger the contact angle (typically in the range 10 to 45 degrees), the higher the axial load supported, but the lower the radial load. In high speed applications, such as turbines, jet engines, and dentistry equipment, the centrifugal forces generated by the balls changes the contact angle at the inner and outer race. Ceramics such as silicon nitride are now regularly used in such applications due to their low density (40% of steel). These materials significantly reduce centrifugal force and function well in high temperature environments. They also tend to wear in a similar way to bearing steel—rather than cracking or shattering like glass or porcelain.
Most bicycles use angular-contact bearings in the headsets because the forces on these bearings are in both the radial and axial dire